| Alejandro Davidovich Fokina vs Matteo Berrettini | 1-2 | 52% | 48% | Matteo Berrettini | 0.275 |
| Adolfo Daniel Vallejo vs Rafael Jodar | 2-0 | 34% | 66% | Adolfo Daniel Vallejo | 0.436 |
| Jaume Munar vs Jaime Faria | 2-0 | 61% | 39% | Jaume Munar | 0.156 |
| Valentin Vacherot vs Stefanos Tsitsipas | 2-1 | 26% | 74% | Valentin Vacherot | 0.550 |
| Kyrian Jacquet vs Luciano Darderi | 2-0 | 72% | 28% | Kyrian Jacquet | 0.077 |
| Arthur Fils vs Frances Tiafoe | 2-0 | 34% | 66% | Arthur Fils | 0.433 |
| Denis Shapovalov vs Alejandro Tabilo | 2-1 | 60% | 40% | Denis Shapovalov | 0.162 |
| Carlos Alcaraz vs Matteo Arnaldi | 2-0 | 93% | 7% | Carlos Alcaraz | 0.005 |
| Matteo Berrettini vs Adolfo Daniel Vallejo | 0-2 | 76% | 24% | Adolfo Daniel Vallejo | 0.583 |
| Ugo Humbert vs Jiri Lehecka | 1-2 | 38% | 62% | Jiri Lehecka | 0.148 |